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Which of the following represents the methyl group?
CH3тАЛ
CH
CH4тАЛ
CH2тАЛ
CH2тАЛ
In a homologous series, successive members differ from each other by a constant unit of тИТCH2тАЛтИТ (methylene group). This addition changes the molecular mass by 14 atomic mass units (amu).
In a homologous series, successive members differ from each other by a constant unit of тИТCH2тАЛтИТ (methylene group). This addition changes the molecular mass by 14 atomic mass units (amu).
Think of it like adding an extra bogie to a train; every time you add one segment, the train gets longer by the same fixed size.
Mnemonic: 'Homologous Series: Add CH2, increase by 14' (Carbon 12 + 2 Hydrogen = 14).
General┬аFormula┬аfor┬аAlkanes:CnтАЛH2n+2тАЛ
Delta┬аMass=12(1)+2(1)=14┬аamu
Members of a homologous series follow the same general formula. For alkanes, this is CnтАЛH2n+2тАЛ. By increasing the value of n by 1 unit (e.g., from n=1 in CH4тАЛ to n=2 in C2тАЛH6тАЛ), one carbon atom and two hydrogen atoms are added, resulting in the characteristic тИТCH2тАЛтИТ increment.
Homologous series members share the same functional group and general formula.
The molecular mass difference between consecutive members is always 14 u.
Physical properties like boiling point and melting point show a gradual increase as molecular mass increases.
Predicting properties of unknown members of a chemical series.
Understanding trends in reactivity within hydrocarbon families.
Atomic mass of Carbon is 12 u and Hydrogen is 1 u, so the mass increment is 12+(2├Ч1)=14 u.
Option D (CH2тАЛ) is correct because every jump from CH4тАЛтЖТC2тАЛH6тАЛ and C2тАЛH6тАЛтЖТC3тАЛH8тАЛ involves gaining one C and two H atoms.
D is correct тАФ Successive members of the alkane homologous series differ by a methylene group, represented as CH2тАЛ.
Remember that for any homologous series, the increment is always the same тИТCH2тАЛтИТ unit, whether it is for alcohols (тИТOH), alkenes, or alkanes.