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Chapter 1 of 12 • Page 1 of 248🔒 Protected PDF • Watermarked
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The electrons in the conduction band are known as _____.
Bound electrons
Valence electrons
Free electrons
None of the above
Free electrons
Quick Summary: Electrons in the conduction band have gained sufficient energy to break free from their parent atoms, making them available for charge conduction. Consequently, they are referred to as free electrons as they are not restricted to a specific atomic site and can move through the crystal lattice under an applied electric field.
Electrons in the conduction band have gained sufficient energy to break free from their parent atoms, making them available for charge conduction. Consequently, they are referred to as free electrons as they are not restricted to a specific atomic site and can move through the crystal lattice under an applied electric field.
Eg=Ec−Ev — Energy bandgap defined by the difference between conduction band edge Ec and valence band edge Ev
J=nevd — Current density where n is the density of free electrons, e is electronic charge, and vd is drift velocity
In a semiconductor, the valence band is filled with electrons bound to atoms. When thermal energy or doping provides energy greater than the bandgap Eg, electrons are promoted to the conduction band. Once in the conduction band, the potential energy landscape allows these electrons to act as mobile charge carriers, facilitating electrical current flow.
Free electrons are the primary charge carriers in n-type semiconductors.
The mobility of free electrons is typically higher than that of holes.
An electron must absorb energy equal to or greater than Eg to become a free electron.
At T=0K, there are no free electrons in an intrinsic semiconductor.
High conductivity when carriers are available
Allows for control of current via external bias
Highly dependent on temperature
Sensitivity to impurities (dopants)
Transistor operation (BJT/FET)
Photodetectors and LEDs
P-N junction rectifiers
Bound electrons are associated with covalent bonds in the valence band.
Option B is incorrect because valence electrons remain associated with the nucleus and do not contribute significantly to conduction.
C is correct — Electrons that have transitioned to the conduction band are called free electrons because they are no longer bound to any specific atom and are free to move throughout the crystal lattice.
Remember that in conductors, the valence and conduction bands overlap, providing a high density of free electrons even at room temperature.