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Back to Practice Questions
ElectricalBasic Electrical
PrevNext

The lead-acid cell should never be discharged beyond

A

1.8 V

B

1.9 V

C

2 V

D

2.1 V

Correct Answer

Concept & PrincipleElectricalBasic Electrical
Option A

1.8 V

Quick Summary: A lead-acid cell should not be discharged below 1.8 V because doing so promotes the formation of large, hard lead sulfate crystals on the plates, a process known as sulfation. This chemical change is difficult to reverse and permanently reduces the battery's capacity and overall service life.

ЁЯТб Explanation

A lead-acid cell should not be discharged below 1.8 V because doing so promotes the formation of large, hard lead sulfate crystals on the plates, a process known as sulfation. This chemical change is difficult to reverse and permanently reduces the battery's capacity and overall service life.

ЁЯФв Key Formulas

Vcell=EтИТIтЛЕrV_{cell} = E - I \cdot rVcellтАЛ=EтИТIтЛЕr тАФ Terminal voltage calculation during load discharge

PbO2+Pb+2H2SO4тЖТ2PbSO4+2H2OPbO_2 + Pb + 2H_2SO_4 \rightarrow 2PbSO_4 + 2H_2OPbO2тАЛ+Pb+2H2тАЛSO4тАЛтЖТ2PbSO4тАЛ+2H2тАЛO тАФ Chemical reaction at discharge

тЪЩя╕П Working Principle

During discharge, active material on both the positive (lead dioxide, PbO2PbO_2PbO2тАЛ) and negative (spongy lead, PbPbPb) plates converts into lead sulfate (PbSO4PbSO_4PbSO4тАЛ). If discharge continues below 1.8 V, the electrolyte density drops significantly, and the PbSO4PbSO_4PbSO4тАЛ converts into a stable, crystalline form that occupies more volume. This accumulation causes plate warping, internal short circuits, and loss of electrolyte porosity, effectively 'killing' the cell.

ЁЯУМ Key Points
  • тЦ╕

    Nominal voltage of a lead-acid cell is 2.0 V.

  • тЦ╕

    Sulfation occurs when a battery is left in a discharged state for too long.

  • тЦ╕

    Specific gravity of the electrolyte is a reliable indicator of state-of-charge.

  • тЦ╕

    Deep discharge cycles significantly shorten cycle life.

тЬЕ Advantages
  • тЦ╕

    High surge current capability

  • тЦ╕

    Low internal resistance

  • тЦ╕

    Cost-effective for high capacity applications

тЭМ Disadvantages / Limitations
  • тЦ╕

    Heavy weight due to lead plates

  • тЦ╕

    Sensitive to deep discharge cycles

  • тЦ╕

    Electrolyte leakage risk

ЁЯЫая╕П Applications / Uses
  • тЦ╕

    Automotive starter batteries

  • тЦ╕

    Uninterruptible Power Supplies (UPS)

  • тЦ╕

    Emergency lighting systems

ЁЯУД Additional Information
  • тЦ╕

    The 1.8 V limit is the 'cut-off' voltage for a standard 2 V cell.

  • тЦ╕

    Option B (1.9 V) is near full discharge but safe; 1.8 V is the absolute safety threshold.

  • тЦ╕

    Option C (2 V) is the nominal voltage, not a discharge limit.

ЁЯУК Diagram / Illustration
Lead-Acid Cell Discharge Limit
VterminalтЙе1.8VV_{terminal} \geq 1.8 VVterminalтАЛтЙе1.8V
Prevents Irreversible Sulfation
тЬЕ

A is correct тАФ The 1.8 V threshold is established to prevent irreversible chemical damage through sulfation.

Core Concepts Used
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Electrochemical discharge Battery Sulfation Cut-off voltage
ЁЯТб EXAM TIP

Always remember that lead-acid batteries fail prematurely due to deep discharge; keep them charged to maintain an electrolyte density of roughly 1.250-1.280 for optimal performance.

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