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In the electrolytic refining of copper, the cathode is made up of:
Pure copper plate
Impure copper rod
Graphite rod
Platinum wire
Pure copper plate
In electrolytic refining, the cathode is made of a thin strip of pure copper. The electrolyte is an aqueous solution of copper sulphate acidified with sulphuric acid.
In electrolytic refining, the cathode is made of a thin strip of pure copper. The electrolyte is an aqueous solution of copper sulphate acidified with sulphuric acid.
Think of it as a 'purification conveyor belt' where dirty copper gets dumped into a pool at the anode and is reassembled perfectly clean onto the cathode mold.
Remember 'AC' for Anode-Crude (impure) and 'CP' for Cathode-Pure.
Cu(s)тАЛтЖТCu(aq)2+тАЛ+2eтИТ тАФ Oxidation at the Anode
Cu(aq)2+тАЛ+2eтИТтЖТCu(s)тАЛ тАФ Reduction at the Cathode
When an electric current is passed through the electrolyte, copper atoms from the impure copper anode lose electrons to form Cu2+ ions and dissolve into the solution. These Cu2+ ions migrate to the pure copper cathode, where they gain two electrons to become neutral copper atoms, effectively plating onto the pure copper strip. The overall net reaction is simply the transfer of pure copper from the anode to the cathode: CuanodeтАЛтЖТCucathodeтАЛ.
The anode is made of thick impure copper.
The electrolyte is acidified CuSO4тАЛ solution.
Impurities like silver, gold, and platinum settle at the bottom of the anode as 'anode mud'.
Electrolytic refining produces copper of 99.99% purity.
Produces extremely high-purity metal
Allows recovery of precious metals like gold and silver from anode mud
High energy consumption due to electricity usage
Requires careful management of acidic chemical waste
Refining of copper for electrical wiring
Manufacturing high-conductivity components for electronics
Copper refining is a crucial industrial process for electrical conductivity.
Option B represents the anode, not the cathode.
Graphite is used as an inert electrode in many processes (like aluminum production) but not for copper refining.
A is correct тАФ The cathode consists of a pure copper plate upon which refined copper ions deposit during electrolysis.
Always remember that in all electrolytic cells, oxidation (loss of electrons) occurs at the anode and reduction (gain of electrons) occurs at the cathode, regardless of the metal being refined.