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ElectricalBasic Electrical
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The best indication about the state of charge on a lead-acid battery is given by

A

output voltage

B

temperature of electrolyte

C

specific gravity of electrolyte

D

none of the above

Correct Answer

Concept & PrincipleElectricalBasic Electrical
Option C

specific gravity of electrolyte

Quick Summary: The specific gravity of the electrolyte is the most accurate indicator of a lead-acid battery's state of charge. As the battery discharges, the sulfuric acid is consumed and the specific gravity of the electrolyte decreases, whereas during charging, the concentration of sulfuric acid increases, raising the specific gravity.

ЁЯТб Explanation

The specific gravity of the electrolyte is the most accurate indicator of a lead-acid battery's state of charge. As the battery discharges, the sulfuric acid is consumed and the specific gravity of the electrolyte decreases, whereas during charging, the concentration of sulfuric acid increases, raising the specific gravity.

ЁЯФв Key Formulas

SG=╧Бelectrolyte╧БwaterSG = \frac{\rho_{electrolyte}}{\rho_{water}}SG=╧БwaterтАЛ╧БelectrolyteтАЛтАЛ тАФ Definition of specific gravity

Pb+PbO2+2H2SO4тЖФ2PbSO4+2H2OPb + PbO_2 + 2H_2SO_4 \leftrightarrow 2PbSO_4 + 2H_2OPb+PbO2тАЛ+2H2тАЛSO4тАЛтЖФ2PbSO4тАЛ+2H2тАЛO тАФ Chemical reaction inside the battery

тЪЩя╕П Working Principle

During the chemical discharge process, sulfuric acid (H2SO4H_2SO_4H2тАЛSO4тАЛ) reacts with the lead (PbPbPb) and lead dioxide (PbO2PbO_2PbO2тАЛ) plates to form lead sulfate (PbSO4PbSO_4PbSO4тАЛ) and water (H2OH_2OH2тАЛO). This dilution of the electrolyte lowers its density. By measuring the specific gravity with a hydrometer, we determine the concentration of the remaining acid, which directly correlates to the remaining capacity.

ЁЯУМ Key Points
  • тЦ╕

    A fully charged lead-acid battery typically has a specific gravity between 1.250 and 1.280.

  • тЦ╕

    A discharged battery generally shows a specific gravity below 1.150.

  • тЦ╕

    Specific gravity measurements must be temperature-compensated as liquid density changes with temperature.

  • тЦ╕

    Hydrometers are the standard instrument used to measure this density.

тЬЕ Advantages
  • тЦ╕

    Provides a direct quantitative measure of chemical health.

  • тЦ╕

    Independent of temporary surface charge effects that skew voltage readings.

тЭМ Disadvantages / Limitations
  • тЦ╕

    Requires physical access to the liquid electrolyte (not possible in sealed/VRLA batteries).

  • тЦ╕

    Measurement is invasive and requires handling of caustic sulfuric acid.

ЁЯЫая╕П Applications / Uses
  • тЦ╕

    Maintenance of flooded lead-acid stationary batteries.

  • тЦ╕

    Automotive battery health diagnostics.

  • тЦ╕

    Industrial UPS systems.

ЁЯУД Additional Information
  • тЦ╕

    Option A (output voltage) is misleading because it varies significantly with the load current (due to internal resistance).

  • тЦ╕

    Option B (temperature) is an environmental variable, not a direct indicator of electrochemical energy storage.

ЁЯУК Diagram / Illustration
Specific Gravity PrincipleMass of ElectrolyteMass of equal Volume of WaterState of Charge тИЭ Specific Gravity
тЬЕ

C is correct тАФ specific gravity of electrolyte provides a direct measurement of the sulfuric acid concentration, which is chemically tied to the battery's state of charge.

Core Concepts Used
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Electrochemical stoichiometry Electrolyte density Hydrometry
ЁЯТб EXAM TIP

Always remember that terminal voltage is a poor indicator of charge under load, whereas specific gravity remains a reliable chemical indicator for flooded-cell technologies.

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