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Chapter 1 of 12 • Page 1 of 248🔒 Protected PDF • Watermarked
Back to Practice Questions
ElectricalBasic Electrical
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When a lead-acid battery is in fully charged condition, the colour of its positive plate is

A

dark grey

B

brown

C

dark brown

D

none of the above

Correct Answer

Concept & PrincipleElectricalBasic Electrical
Option B

brown

Quick Summary: In a fully charged lead-acid battery, the active material of the positive plate consists of Lead Peroxide ($PbO_2$), which exhibits a characteristic dark brown color. The negative plate, composed of sponge lead ($Pb$), appears grey or slate grey.

💡 Explanation

In a fully charged lead-acid battery, the active material of the positive plate consists of Lead Peroxide (PbO2PbO_2PbO2​), which exhibits a characteristic dark brown color. The negative plate, composed of sponge lead (PbPbPb), appears grey or slate grey.

🔢 Key Formulas

PbSO4+2H2O→chargePbO2+H2SO4+H2PbSO_4 + 2H_2O \xrightarrow{\text{charge}} PbO_2 + H_2SO_4 + H_2PbSO4​+2H2​Ocharge​PbO2​+H2​SO4​+H2​ — Positive plate charging reaction

⚙️ Working Principle

During the charging process, the electrical energy induces a chemical reaction where lead sulfate (PbSO4PbSO_4PbSO4​) on the plates is converted. At the positive plate, PbSO4PbSO_4PbSO4​ reacts with the electrolyte and water to form Lead Peroxide (PbO2PbO_2PbO2​), which is dense and dark brown in color. The reaction is: PbSO4+2H2O+SO4°2−→PbO2+2H2SO4PbSO_4 + 2H_2O + SO_4°{2-} \rightarrow PbO_2 + 2H_2SO_4PbSO4​+2H2​O+SO4​°2−→PbO2​+2H2​SO4​.

📌 Key Points
  • ▸

    Positive plate is made of Lead Peroxide (PbO2PbO_2PbO2​).

  • ▸

    Negative plate is made of Sponge Lead (PbPbPb).

  • ▸

    State of charge can be visually estimated by plate color.

  • ▸

    Fully discharged plates appear white due to the accumulation of lead sulfate.

✅ Advantages
  • ▸

    High surge current capability

  • ▸

    Low self-discharge rate compared to other rechargeable chemistries

❌ Disadvantages / Limitations
  • ▸

    Low energy-to-weight ratio

  • ▸

    Risk of sulfation if left in a discharged state

🛠️ Applications / Uses
  • ▸

    Automotive starting, lighting, and ignition systems

  • ▸

    Uninterruptible Power Supplies (UPS)

📄 Additional Information
  • ▸

    As the battery discharges, the dark brown PbO2PbO_2PbO2​ is converted back to white PbSO4PbSO_4PbSO4​, causing the plate color to lighten.

  • ▸

    Option A (Dark Grey) is incorrect as it typically describes the negative plate or a partially discharged positive plate.

📊 Diagram / Illustration
Lead-Acid Battery PlatesPositive PlatePbO2 (Dark Brown)Negative PlatePb (Grey)
✅

C is correct — The positive plate of a fully charged lead-acid battery is dark brown because it consists of lead peroxide (PbO2PbO_2PbO2​).

Core Concepts Used
Click any tag to open in AI Tutor
Electrochemical energy storage Active plate materials Lead-acid charging chemistry
💡 EXAM TIP

Always remember: PbO2PbO_2PbO2​ (positive) is dark brown, PbPbPb (negative) is grey, and PbSO4PbSO_4PbSO4​ (discharged/sulfated) is white/light grey.

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